A microporous indium-organic framework with high capacity and selectivity for CO2 or organosulfurs.
نویسندگان
چکیده
Presented here is a multifunctional microporous indium-organic framework material with doubly linked MIL-88D structure, which exhibits high surface area, excellent CO(2)/N(2) adsorption selectivity, good hydrogen storage ability and notable desulfurization behavior.
منابع مشابه
Carbon Dioxide Capture on Metal-organic Frameworks with Amide-decorated Pores
CO2 is the main greenhouse gas emitted from the combustion of fossil fuels and is considered a threat in the context of global warming. Carbon capture and storage (CCS) schemes embody a group of technologies for the capture of CO2 from power plants, followed by compression, transport, and permanent storage. Key advances in recent years include the further development of ne...
متن کاملEffect of ligand geometry on selective gas-adsorption: the case of a microporous cadmium metal organic framework with a V-shaped linker.
A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.
متن کاملStudy of the dynamic adsorption process of toluene by a microporous copper metal-organic framework
Introduction: Toluene is considered as a group of chemical contaminants, causing problems for people’s health. Due to the high rate of evaporation and rapid emission in the surrounding environment, it leads to the exposure of many employees and people at risk and, subsequently, its irreparable effects on their health in different jobs. Therefore, its removal is very important. In the present st...
متن کاملTriptycene-Based Microporous Polymer Incorporating Thioamide Functionality: Preparation and Gas Storage Properties
Triptycene-based micorporous polymer was functionalized with thioamide moieties via post-polymerization using phosphorus pentasulfide as a thionating agent in the presence of sodium sulfite. Gas adsorption experiments indicate that the modification leads to a reduction in the BET surface area of the polymer, from 1640 m g for the parent TMP to 207 m g on 74% conversion of nitrile to thioamide, ...
متن کاملCatalytic Aerobic Oxidation of Alkenes by Ag@Metal Organic Framework with High Catalytic Activity and Selectivity
By coupling of Fe2O3@SiO2 particles with metal organic Framework (MOF) the magnetic MOF structure was fabricated. Precipitation and hydrothermal methods were applied for synthesis of core and MOF. Silver nanoparticles were deposited on nickel based metal organic framework surface and magnetic Fe2O3@SiO2@MOF@Ag was obtained. Because of strong coupling between silver nanoparticles and metal organ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 41 10 شماره
صفحات -
تاریخ انتشار 2012